J. Technology and Education, Vol.29, No.2, pp.43-46 (2022)
研究論文
Ni−P電析膜作製におけるマイクロバブルの効果
戸嶋 茂郎*1,高橋 樂龍2,八幡 有美3
1 鶴岡工業高等専門学校 創造工学科(〒999-8511 山形県鶴岡市井岡字沢田104)
2 鶴岡工業高等専門学校専攻科 生産システム工学専攻(〒999-8511 山形県鶴岡市井岡字沢田104)
3 平岡織染株式会社 技術本部(〒340-0013 埼玉県草加市松江4-1-8)
*shigero@tsuruoka-nct.ac.jp
Effects of Microbubble on Ni-P Electrodeposition
Shigero TOSHIMA*1 , Garyo
TAKAHASHI2 and Ami YAHATA3
1 Department of
Creative Engineering, National Institute of Technology, Tsuruoka
College
(104 Sawada, Inooka,Tsuruoka, Yamagata 999-8511 Japan)
2 Department of Advanced
Engineering Course, National Institute of Technology, Tsuruoka
College
(104 Sawada, Inooka,Tsuruoka, Yamagata 999-8511 Japan)
3 Technical R&D
Div., HIRAOKA & CO.,LTD.
(4-1-8 Matsue, Soka, Saitama 340-0013 Japan)
(Received July 26, 2022; Accepted September
20, 2022)
Abstract
We investigated the effect
of microbubble dispersion in a Watts-type Ni bath containing phosphorous acid
on the chemical composition and crystal structure of Ni-P alloy electrodeposition. The presence of microbubbles during electrodeposition
was found to accelerate the co-deposition of phosphorus into deposits,
resulting in the amorphization of the Ni-P deposit.
Key words : Microbubble, Electrodeposition, Ni-P
Alloy, Amorphous