J. Technology and Education, Vol.31, No.1, pp.1-5 (2024)

研究論文

ヘテロ環が置換したフタロシアニン化合物の合成と同定

 

松井 栄樹*、冨原 颯太、栗原 廉

福井工業高等専門学校　物質工学科（〒916-8507　福井県鯖江市下司町）

*eiki@fukui-nct.ac.jp

 

Synthesis and characterization of phthalocyanine compounds

substituted with heterocycles

再試行しています..

Eiki MATSUI*, Souta TOMIHARA, Ren KURIHARA

Department of Chemistry and Biology, National Institute of Technology, Fukui College

(Geshi, Sabae, Fukui 916-8507, Japan)

 

(Received December 24, 2023; Accepted January 29, 2024)

Abstract

   The synthesis and characterization of new functionalized phthalocyanines directly condensed with heterocyclic moieties are described. These phthalocyanine compounds (Pcs) formed from planar heterocycles contain four extra metal-binding sites, and one of them is formed by three nitrogen atoms and other heteroatoms. The synthesis of Pcs was carried out in two or three stages, and the formation of Pcs was confirmed by UV–Vis absorption spectrum and MALDI–MS measurement. The design strategy and optical properties of Pcs help to extend the development of phthalocyanine-based cancer photodynamic therapy (PDT).

Keywords: phthalocyanine, heterocyclic substitution, binding sites, metal ion binding